16. Angelina Jolie and Billy Bob Thornton

Another wild pairing of the early 2000s was between actress Angelina Jolie and actor Billy Bob Thornton. The couple had a high-profile romance and were very public in showing their affection. The two stayed married for only two years from 2000 to 2003 and it is safe to say, that this one was a wild romance.
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Edited by Tanisha Aggarwal