10. Tywin Lannister

Tywin Lannister, the calculating patriarch of House Lannister, died in the most ironically unexpected way. After being freed from imprisonment, Tyrion finally approached his father in the privy, where he found his father's infidelity with Shae. Consumed by rage, he shot Tywin with a crossbow and killed him- the man who had belittled his existence throughout his life. The death of Tywin was both a fall for one of Westeros' greatest powers and an ultimate rebellion on the part of Tyrion against his family. This was a mix of personal revenge and poetic justice, leaving both fans stunned but satisfied.
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